The goalkeeper with the most clean sheets is Edwin Vandersar. with 13 clean sheets for Manchester United.
It was the Italian Zenga.
1. Joe Hart, 14 2. Wojciech Szczesny, 12 3. David De Gea, 11
Most sheets are made out of cotton, which is a fabric.
David James 172 - Mark Schwarzer 149 - David Seaman 144 - Petr Cech 143 - Nigel Martyn 140
Most clean sheets in one season: 24, Petr Čech (for Chelsea, 2004-05) Most clean sheets in Premiership history: 143 (as May 14, 2007), David James http://en.wikipedia.org/wiki/Football_records_in_England#Goalkeepers
Pepe Reina (Liverpool) and David James (Currently Retired). They have held the most clean sheets.
It is Arsenalfc with 49 clean sheets including the current season (2012-13).