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Yes, Serena has defeated Venus many times, and same goes that other way. They are rivals for that reason.
Serena Williams
3, one singles and 2 doubles
sarena willams known 4 tennis. . .. . . .. The world best tennis player. . . . . 2DAY willams celebrates b'DAY that is 26 sept 1981. . .. any way hats of to willams. . . .
As of 2014, Serena Williams has won the Australian Open Women's Singles 5 times and Women's doubles 4. She won the women's single title in 2003, 2005, 2007, 2009, and 2010. Serena also win the Women's doubles title with her sister Venus Williams in 2001, 2003, 2009 and 2010.
Sisters Venus and Serena Williams have met in the Wimbledon women's singles final four times: 2002, 2003, 2008 and 2009 with Serena winning 3 times.
1, Caroline Wozniacki 2, Serena Williams 3, Vera Zvonareva 4, Venus Williams 5, Kim Clijsters
Venus and Serena Williams have, as of June 2012, met a total of 4 times in a Wimbledon final. Venus has won 1 of these matches (2008) and Serena has won 3 of these meetings (2002, 2003 and 2009) In addition to this, they also met each other in the 2000 semi final, which was won by Venus.
He has won player of the West aproximately 46 times.
Three times
13 times
Dikembe Mutombo and Ben Wallace have both won this award four times.