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Chile were eliminated from the 2014 FIFA World Cup in the Round of 16 on June 28, having lost to hosts Brazil in a penalty shootout. Both teams were tied 1-1 after both periods of added extra time, resulting in the penalty shootout tiebreaker where Brazil scored three and Chile only scored two.

Notably, Chile have never defeated Brazil on Brazilian home soil in 27 matches, with 21 losses (including the 2014 FIFA World Cup Round of 16 match), 6 draws, and no wins.

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