I believe there is no "actual" prime minister of Venezuela.
Damte Rivas is the Minister of Commerce for Venezuela.
Fidel Barbarito is the Minister of Culture for Venezuela.
Hector Rodriguez is the Minister of Education for Venezuela.
Francisco Armada is the Minister of Health for Venezuela.
Ricardo Menendez is the Minister of Planning for Venezuela.
Andres Izarra is the Minister of Tourism for Venezuela.
Jesse Chacon is the Minister of Electricity for Venezuela.
Victor Clark is the Minister of Youth for Venezuela.
Miguel Tadeo Rodriguez is the Minister of Environment for Venezuela.
Jose David Cabello is the Minister of Industry for Venezuela.
Herbert Garcia Plaza is the Minister of Nutrition for Venezuela.