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No, Spain's 0-2 defeat at the hands of Chile in their second Group Stage match on 18 June 2014 guaranteed their elimination from the 2014 FIFA World Cup.
In the Group Stage of the tournament, only the group winners and the runners-up of a Group advance to the Round of 16. Because both the Netherlands and Chile won two out of three matches each, both teams were guaranteed the top two spots in Group B. Meanwhile, Australia and Spain were unable to advance beyond the Group Stage.
As a result, Spain became the first team in the 2014 FIFA World Cup to be eliminated, followed by Australia and Cameroon the same day. This marked the first time a defending world champion (Spain) was effectively eliminated from the tournament having only played two matches.
Ultimately, Spain ended their 2014 FIFA World Cup campaign with a 3-0 victory over Australia in their final Group Stage match on June 23.
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